Solar Hydrogen

Hydrogen is an energy-dense, zero-carbon fuel suitable for a range of energy applications which currently have no viable alternative to fossil fuels. In order to decarbonise the energy sector however, we will need an abundant supply of low-cost hydrogen, produced from clean energy sources. Renewable hydrogen can be produced from renewable energy driven electrolysis, but is not currently competitive with fossil fuel sources of hydrogen.

Instead, we are looking at new ways of producing hydrogen directly from sunlight and water. In direct solar hydrogen production, light provides the energy to drive the water splitting redox reaction (via the photovoltaic effect), resulting in hydrogen production in a single integrated system. 

The aim of this project is to design, fabricate and integrate low-cost semiconductors and catalysts for direct solar-to-hydrogen production systems. Analogous to solar power, high solar energy to hydrogen conversion (STH) efficiencies are key to low-cost renewable hydrogen. We are leveraging the rapid advancement in Silicon/Perovskite tandem cells, combined with high performance, low-cost catalysts to design robust integrated solar-driven water splitting systems.

Our work focuses on:

  • designing a range of photovoltaic semiconductor devices, both cells and photoelectrodes specifically for standalone water splitting;
  • developing low-cost, high-efficiency catalysts and co-catalysts;
  • integration of photovoltaic and electrochemical components for systems with maximum efficiency;
  • and developing analytical models to identify performance limitations and to conceptualize optimal device designs

Publications 

  1. D. Zhang, J. Z. Soo, H. H. Tan, C. Jagadish, K. Catchpole, S. Karuturi, Earth-Abundant Amorphous Electrocatalysts for Electrochemical Hydrogen Production: A Review, Advanced Energy and Sustainability Research, (2021), 2, 2000071, https://doi.org/10.1002/aesr.202000071
  2. Y. Wang, A. Sharma, T. Duong, H. Arandiyan , T. Zhao, D. Zhang, Z. Su, M. Garbrecht, F. J. Beck, S. Karuturi, C. Zhao, and K. Catchpole, Direct Solar Hydrogen Generation at 20% Efficiency Using Low-Cost Materials, Advanced Energy Materials, Accepted 2021 https://doi.org/10.1002/aenm.202101053
  3. A. Sharma, F. J. Beck, Quantifying and Comparing Fundamental Loss Mechanisms for Solar Hydrogen Generation, Advanced Energy and Sustainability Research, (2020) https://doi.org/10.1002/aesr.202000039
  4. S. Karuturi, H. Shen, A. Sharma, F. J. Beck, P. Varadhan, T. Duong, P. R. Narangari, D. Zhang, Y. Wan, J. He, H. H. Tan, C. Jagadish, K. Catchpole, Over 17% Efficiency Stand‐Alone Solar Water Splitting Enabled by Perovskite‐Silicon Tandem Absorbers, Advanced Energy Materials, 10, 28, 2000772, (2020) https://onlinelibrary.wiley.com/doi/abs/10.1002/aenm.202000772
  5. F.J. Beck, Rational Integration of Photovoltaics for Solar Hydrogen Generation, ACS Appl. Energy Mater. 2, 9, 6395-6403 (2019) https://pubs.acs.org/doi/10.1021/acsaem.9b01030

Funding

This project is funded by the Australian Renewable Energy Agency: Efficient solar hydrogen generation

Partners

UNSW

Updated:  10 August 2021/Responsible Officer:  Dean, CECS/Page Contact:  CECS Marketing